Magnesia-chrome refractory brick


Technical Specifications for Alkaline Refractory Bricks—Magnesia-Chrome Bricks Main Type: Direct-Bonded Magnesia-Chrome Brick (MG-15) Composition: MgO 60–70%, Cr₂O₃ 12–18% Characteristics: Direct-bonding ratio ≥85% at 1700°C; Thermal-shock resistance: ≥30 cycles (water quenching at 1100°C) Electrofused Re-bonded Magnesia-Chrome Brick (MGR-20): Electrofused synthetic material content ≥80%; Apparent porosity ≤14%; Slag penetration resistance improved by 50%. Production Process: Pre-sintering of raw materials (magnesia sand at 1800°C, chromite ore at 1600°C); High-pressure forming (300–400 MPa); Ultra-high-temperature firing (1750–1850°C for 24 hours); Dimensional finishing with precision ±0.3 mm. Technical Specifications for Magnesia-Alumina Bricks Innovative Type: Spinel-Reinforced (MA-85): MgO 80–85%, Al₂O₃ 10–15%; Spinel phase ≥25%; Thermal conductivity: 2.1 W/(m·K). Gradient Composite Magnesia-Alumina Brick: Working face—corundum coating (100 μm); Transition layer—MgO/Al₂O₃ = 70/30; Backing layer—porous structure (porosity 30%). Key Processes: Spinel pre-synthesis at 1600°C; Nano-scale batching (D50 ≤1 μm); Atmosphere-controlled sintering under nitrogen protection. Technical Specifications for Magnesia-Zirconia Bricks New Product: Zirconia-Toughened (MZ-10): ZrO₂ 8–12% (sub-micron grade); Fracture toughness increased threefold; Excellent creep resistance at 1700°C. Magnesia-Zirconia Composite Brick (MZ-20): MgZrO₃ as the primary crystalline phase; Enhanced alkali-corrosion resistance by 60%; Life-cycle cost reduced by 40%. Application Comparison and Analysis: Optimal Application Scenarios and Economic Benefits Magnesia-Chrome Brick: Copper-smelting furnace slag line—service life 12–18 months (compared with the conventional 8 months). Magnesia-Alumina Brick: Cement kiln transition zone—thermal consumption reduced by 0.8 GJ per ton of clinker. Magnesia-Zirconia Brick: Glass-furnace regenerator—maintenance interval extended to 5 years. Physicochemical Performance Comparison (GB/T 2026): | Indicator | Magnesia-Chrome Brick | Magnesia-Alumina Brick | Magnesia-Zirconia Brick | |-------------------------|-----------------------|-----------------------|-----------------------| | Load-Softening Point (°C) | ≥1700 | ≥1650 | ≥1680 | | Thermal-Shock Resistance (cycles) | 30 | 35 | 25 | | Slag Penetration (mm) | ≤1.5 | ≤2.0 | ≤1.0 | Environmental Indicators: - Hexavalent chromium leaching: ≤0.07 mg/L (new chromium-free product); - Heat recovery rate: ≥75% (recycling of waste bricks).

Alkaline refractory brick

Technical Specification for Magnesia-Chrome Bricks

Main Types

  1. Direct-bonded magnesia-chrome bricks ( MG-15)
  • Ingredients: MgO 60–70%, Cr₂O₃ 12–18%
  • Features: Direct bonding rate ≥85% at 1700℃
  • Thermal shock resistance: ≥30 cycles (1100°C water cooling)
  1. Electrofused re-bonded magnesia-chrome brick ( MGR-20)
  • Electrofused synthetic material ≥80%
  • Apparent porosity ≤ 14%
  • Enhanced slag resistance 50%

Production process

  1. Raw material pre-firing (magnesia) 1800℃, chromite ore 1600℃)
  2. High-pressure molding ( 300–400 MPa)
  3. Ultra-high temperature firing ( 1750–1850°C/24 h)
  4. Dimensional finishing (accuracy ±0.3 mm)

Technical Specification for Magnesia-Alumina Bricks

Type of Innovation

  1. Spinel-reinforced ( MA-85)
  • MgO 80–85%, Al₂O₃ 10–15%
  • Spinel phase ≥25%
  • Thermal conductivity: 2.1 W/(m·K)
  1. Gradient Composite Magnesia-Alumina Brick
  • Working surface: Corundum coating ( 100 μm)
  • Transition layer: MgO/Al₂O₃ = 70/30
  • Backer layer: Porous structure (porosity 30%)

Key Process

  1. Spinel pre-synthesis ( 1600℃)
  2. Nanometer-scale ingredients ( D50 ≤ 1 μm)
  3. Atmosphere-Controlled Sintering (Nitrogen Protection)

Technical Specification for Magnesium-Zirconia Bricks

New product

  1. Zirconia-toughened ( MZ-10)
  • ZrO₂ 8–12% (sub-micron grade)
  • Improved fracture toughness 3 times
  • Excellent creep resistance at 1700℃
  1. Magnesium zirconate composite brick ( MZ-20)
  • MgZrO₃ primary crystalline phase
  • Enhanced alkali resistance 60%
  • Reduced life-cycle cost 40%

 

 

 

 

 

Application Comparative Analysis

Brick type

Best Use Cases

Economic benefits

Magnesium-chromium brick

Copper Smelting Slag Line

Lifespan: 12–18 months (traditional: 8 months)

Magnesium-aluminum brick

Cement Kiln Transition Zone

Heat consumption reduced by 0.8 GJ per ton of clinker

Magnesium-zirconia brick

Glass furnace regenerator

Maintenance interval extended to 5 years

Physicochemical indicators

  1. High-Temperature Performance Comparison ( GB/T 2026 ):

| Indicator Magnesium-chromium brick Magnesium-aluminum brick Magnesium-zirconia brick |

| Load-Softening Point (℃) | ≥1700 | ≥1650 | ≥1680  |

| Thermal shock stability ( next time   | 30 | 35 | 25  |

| Slag resistance (mm) | ≤1.5   | ≤2.0 | ≤1.0   | 

  1. Environmental protection indicators:

- Hexavalent chromium leaching amount: ≤0.07 mg/L (New-type chromium-free product)

- Heat recovery rate: ≥75% (Waste Brick Recycling)

 


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Magnesia-chrome refractory brick

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