Zirconia Special-Shaped Brick


Zirconia–Silica Refractory Bricks I. Main Product Types Standard Zirconia–Silica Brick (ZS-65): Composition: ZrO₂ 65±2%, SiO₂ 32±2%. Characteristics: Bulk density 3.5–3.8 g/cm³; apparent porosity ≤18%. Applications: Upper structures of glass furnaces. Zirconia-Enhanced Type (ZSM-75): Contains 8–12% monoclinic ZrO₂, increasing thermal shock resistance to 25 cycles under 1100°C water quenching. Suitable for tundish permeable bricks. Composite Zirconia–Mullite Gradient Structure (ZrO₂ gradient from 40% to 15%): Thermal conductivity reduced by 30%. II. Intelligent Production Process Raw Material Processing: Microwave calcination of zircon sand at 1500°C for 2 hours. Particle size control: #3–1 mm: 1–0.1 mm; <0.1 mm. Low-Temperature Bonding Technology: Aluminum phosphate binder (firing temperature reduced to 1450°C), reducing CO₂ emissions by 40%. Digital Firing System: Hydrogen-fired shuttle kiln operating at 1600°C ±5°C, with an intelligent temperature-control module providing independent regulation in 30 zones. III. Application Scenarios and Typical Cases—Performance Data Electronic glass high-borosilicate melting furnace arch: Service life extended to 7 years. New-energy photovoltaic glass tin bath: Energy consumption reduced by 22%. Aerospace rocket nozzle insulation layer: Temperature resistance up to 2000°C. Environmental hazardous-waste incinerator lining: Corrosion resistance improved by 50%. IV. Performance Advantages Compared with Traditional Materials Resistance to glass erosion: 0.5 mm/year (compared with 1.2 mm for AZS bricks). Thermal-shock stability: 20 cycles (versus only 5 for silica bricks). Economic Analysis: Cost 35–40% lower than AZS bricks; maintenance interval of 5 years, eliminating major overhauls. V. Latest Physicochemical Specifications 1. Basic Properties (ZS-65): – Bulk density: 3.65±0.15 g/cm³ (GB/T 2997-2025); – Compressive strength: ≥80 MPa (ISO 10059-2:2026). 2. High-Temperature Characteristics: – Load-softening point: ≥1680°C (at 0.2 MPa); – Coefficient of thermal expansion: 0.45% (at 1000°C). 3. Special Indicators: – Resistance to sodium–calcium glass erosion: ≤0.8 mm/24 h (at 1500°C); – Radioactivity: Internal radiation index ≤0.3.

Zirconia refractory brick

I. Main Product Types

  1. Standard zircon brick ( ZS-65)
  • Ingredients: ZrO₂ 65±2%, SiO₂ 32±2%
  • Characteristic: Bulk Density 3.5–3.8 g/cm³, apparent porosity ≤ 18%
  • Application: Upper Structure of Glass Furnace
  1. Zirconia-reinforced ( ZSM-75)
  • Add 8–12% monoclinic ZrO₂
  • Thermal shock resistance improved to 25 cycles (water cooling at 1100℃)
  • Applicable: Ladle breathable bricks
  1. Composite
  • Zircon -Mullite gradient structure (ZrO₂ gradient from 40% to 15%)
  • Reduced thermal conductivity 30%

II. Intelligent Production Processes

  1. Raw Material Processing

Microwave calcination of zircon sand ( 1500℃/2h )

Particle Size Control:

# 3–1 mm: 1–0.1 mm: <0.1 mm ```

 

  1. Low-temperature bonding technology
  • Aluminum phosphate binder (sintering temperature reduced to 1450℃)
  • 40% reduction in CO₂ emissions
  1. Digital Sintering System
  • Hydrogen-fired shuttle kiln ( 1600℃±5℃)
  • Intelligent temperature control module ( Independent regulation in Zone 30)

 

 

 

III. Applications

Application Scenarios

Typical Cases

Performance Data

Electronic glass

High-borosilicate melting furnace arch

Life expectancy extended to 7 years

New energy

Photovoltaic Glass Tin Bath

Energy consumption reduced by 22%

Aerospace

Rocket nozzle insulation

Temperature resistance of 2000℃

Environmental protection

Lining for Hazardous Waste Incinerators

50% improvement in erosion resistance

IV. Performance Advantage Comparison

  1. Comparison with Traditional Materials
  • Resistance to glass corrosion: 0.5 mm/year (AZS brick: 1.2 mm)
  • Thermal shock stability: 20 times (only 5 times for silica bricks)
  1. Economic Analysis
  • Cost: Compared to AZS bricks are 35–40% lower
  • Maintenance cycle: 5-year major overhaul exemption

V. Latest Physicochemical Indices

1. Basic Performance ( ZS-65 ): Bulk density: 3.65±0.15 g/cm³ GB/T 2997-2025 ) Withstand Voltage Strength: ≥80MPa ISO 10059-2:2026 )

2. High-temperature characteristics: Load-softening point: ≥1680℃ 0.2MPa ) Coefficient of thermal expansion: 0.45% 1000℃ )

3. Special indicators: Resistance to sodium-calcium glass corrosion: ≤0.8 mm/24 h 1500°C ) Radioactivity: Internal Exposure Index ≤0.3


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Zirconia Special-Shaped Brick

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