Low Thermal Conductivity Mullite Composite Brick


Main Types of Low-Thermal-Conductivity Mullite Composite Refractory Bricks Low‑thermal‑conductivity mullite composite refractory bricks are classified into three categories based on their structure: homogeneous low‑thermal‑conductivity bricks; multilayer composite bricks; and zirconia–mullite bricks. The core of the production process focuses on reducing the thermal conductivity coefficient: Raw Material Processing: Low‑impurity aggregates such as tabular corundum and electrofused mullite are selected, with Fe₂O₃ content controlled at ≤0.6%. Structural Compositing: Multilayer bricks employ a gradient batching approach (with the working layer containing ≥70% Al₂O₃ and the insulation layer containing ≤65%), followed by isostatic pressing and sintering at 1700°C.

Main Types of Low Thermal Conductivity Mullite Composite Refractory Bricks

Low thermal conductivity mullite composite refractory bricks are classified into three types according to their structure:

  1. Homogeneous low‑thermal‑conductivity brick : With The material is primarily a 60/70-grade mullite homogenate, with fine redscheelite (Al₂SiO₅) powder added to optimize thermal shock resistance. The Al₂O₃ content ranges from 55% to 75%, and the bulk density is 2.0–2.2 g/cm³.
  2. Multi-layer composite brick : Work layer ( M70 mullite + 12% silicon carbide), insulation layer (M60 mullite), and thermal barrier layer (zirconia fiberboard), with a thermal conductivity of only 1.2 W/(m·K) at 1000℃.
  3. Zirconia-mullite brick : Introducing zircon sand ( ZrSiO₄) undergoes phase transformation toughening, with a bulk porosity of 18%–22% and a spalling resistance of up to 20 cycles (water cooling at 1100°C).

 


 

Production Process

Core process focuses on reducing thermal conductivity:

  • Raw Material Processing : Select low‑impurity aggregates such as tabular corundum and electrofused mullite, and control… Fe₂O₃ ≤ 0.6%.
  • Structural composite : Multi-layer bricks use a graded mix (working layer Al₂O₃ ≥ 70%, insulation layer ≤ 65%), sintered at 1700°C after isostatic pressing.
  • Micropore Technology : Add pore-forming agents (such as polystyrene spheres) to create closed pores, increasing the porosity to… 25%–30%.
  • Zirconia-mullite synthesis : Bauxite and zircon in A ZrO₂–mullite interwoven structure is formed through a 1600℃ reaction.

 


 

Application Scenarios

  1. Cement Kiln Transition Zone : Replace silicon carbide bricks to reduce kiln shell temperature. At 50–80°C, coal consumption per ton of clinker is reduced by 0.3 kg.
  2. Glass melting furnace : Heat‑storage chamber grid, resistant to alkali vapor erosion ( Na₂O penetration depth < 1 mm).
  3. Petroleum Cracking Furnace Radiation section lining, resistant to… 1100℃ sulfur‑containing flue gas.
  4. Ceramic Roller Kiln : Directly exposed to the flame zone ( 1400℃), and its thermal shock resistance is superior to that of traditional high-alumina bricks.

 


 

Performance Advantages

  1. Ultra-low thermal conductivity At 1000℃, the thermal conductivity is 1.2 W/(m·K), which is 60% of that of silicomosite bricks.
  2. High-temperature stability : The softening temperature of the alloy is ≥1650℃, and the creep rate at 1600℃ is <0.5%.
  3. Significant energy savings Annual Emission Reduction from Cement Kiln Applications Approximately 2,700 tons of CO₂ per line.
  4. Longevity Design : Remaining It can still be used safely at a thickness of 120mm (traditional bricks require the kiln to be shut down for replacement).

 


 

Physicochemical Indicators

Indicator

Homogeneous brick

Multi-layer composite brick

Test standards

Al₂O₃ content

65%–75%

55%–70%

GB/T 6900

Bulk density (g/cm³)

2.0–2.2

1.8–2.0

GB/T 2998

Compressive Strength (MPa)

≥50

≥35

GB/T 5072

Thermal Conductivity (1000℃)

≤1.5 W/(m·K)

≤1.2 W/(m·K)

YB/T 4130

Thermal Shock Stability (cycles)

≥15

≥25

GB/T 30873

 

Note: Composite bricks offer the best overall performance, but they are costly. 20%–30%; zirconia-mullite bricks are more suitable for applications with fluctuating operating temperatures.


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Low Thermal Conductivity Mullite Composite Brick

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